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class="introTitle"> 煙氣脫硫技術(shù) </h1> <ul class="e_box p_dataSource borderB_dividers"> <li><span><span id="g3gg5xt16r9" class="i_sort">分類(lèi)：</span></span><a href=''>技術(shù)與解決方案</a></li>  <li><span><span id="g3gg5xt16r9" class="i_date">發(fā)布時(shí)間：</span></span>2019-10-29 00:00:00</li> <li><span><span id="g3gg5xt16r9" class="i_pv">訪(fǎng)問(wèn)量：</span></span><span id="g3gg5xt16r9" class="p_viewCount">0</span></li> </ul> <div id="g3gg5xt16r9" class="e_box p_summary summary-mo color_minor borderB_bar"> <span><span id="g3gg5xt16r9" class="i_summary">概要:</span></span>離子液法脫除和回收二氧化硫技術(shù) </div> <div id="g3gg5xt16r9" class="e_box p_summary summary-pc color_minor"> <span><span id="g3gg5xt16r9" class="i_summary">概要:</span></span>離子液法脫除和回收二氧化硫技術(shù) </div> <div id="g3gg5xt16r9" class="e_HtmlEditor p_content"> <div id="g3gg5xt16r9" class="e_title p_tit borderB_dividers"><span id="g3gg5xt16r9" class="i_detailTitle">詳情</span></div> <div id="g3gg5xt16r9" class="e_box p_con"><div id="g3gg5xt16r9" class="reset_style js-reset_style js-adapMobile "> <p class="normalPara" style="text-align: center;"><span style="font-size:22px;"><span style="font-family:微軟雅黑體,tahoma,arial,sans-serif;"><strong>復合胺（離子液）法煙氣脫硫技術(shù)</strong></span></span></p> <p class="normalPara" style="text-align: center;"> </p> <p style="text-align: center;"><img class="imageResponse js-onerror" id="0" src="/repository/image/7511eb69-5bff-4338-994c-f9f6c8469a42.gif?t=1711075489544" style="width: 920px; margin-top: 0px; margin-bottom: 0px; height: 571px;" /></p> <div> </div> <div style="margin-left: 80px;"><span style="font-family:楷體_gb2312,tahoma,arial,宋體,sans-serif;"><span style="font-size:18.7px;"><strong>　　技術(shù)原理</strong></span></span></div> <div style="margin-left: 80px;"> </div> <div style="margin-left: 80px;"><span style="font-family:楷體_gb2312,tahoma,arial,宋體,sans-serif;"><span style="font-size:18.7px;">　　與典型的有機溶劑不一樣，在復合胺（離子液）液體里沒(méi)有電中性的分子，100%是陰離子和陽(yáng)離子，在室溫或接近室溫下呈液體狀態(tài)，復合胺（離子液）液體的主要特點(diǎn)：（1）復合胺（離子液）液體一般沒(méi)有蒸汽壓，所以在使用過(guò)程中不產(chǎn)生對大氣造成污染的有害氣體；（2）可以通過(guò)采用不同的陰、陽(yáng)離子組合來(lái)調節復合胺（離子液）液體的物理和化學(xué)性質(zhì)；即復合胺（離子液）液體具有優(yōu)良的可設計性,可以通過(guò)分子設計獲得特殊功能的復合胺（離子液）液體。因此，復合胺（離子液）液體被稱(chēng)為“綠色可設計溶劑”。</span></span></div> <div style="margin-left: 80px;"> </div> <div style="margin-left: 80px;"><span style="font-family:楷體_gb2312,tahoma,arial,宋體,sans-serif;"><span style="font-size:18.7px;">　　本工藝采用的吸收劑是以有機陽(yáng)離子、無(wú)機陰離子為主，添加少量活化劑、抗氧化劑組成的水溶液；該吸收劑對SO<sub>2</sub>氣體具有良好的吸收和解吸能力；其脫硫機理如下：</span></span></div> <div style="margin-left: 80px;"> </div> <div style="margin-left: 80px;"><span style="font-family:楷體_gb2312,tahoma,arial,宋體,sans-serif;"><span style="font-size:18.7px;">　　SO<sub>2</sub>+H<sub>2</sub>O ←→ H<sup>+</sup> + HSO<sub>3</sub><sup>-</sup>　　　　　　　(1)</span></span></div> <div style="margin-left: 80px;"><span style="font-family:楷體_gb2312,tahoma,arial,宋體,sans-serif;"><span style="font-size:18.7px;">　　R+H<sup>+</sup>←→ RH<sup>+</sup>　　　　　　　　　　　　(2)</span></span></div> <div style="margin-left: 80px;"> </div> <div style="margin-left: 80px;"><span style="font-family:楷體_gb2312,tahoma,arial,宋體,sans-serif;"><span style="font-size:18.7px;">總反應式：</span></span></div> <div style="margin-left: 80px;"><span style="font-family:楷體_gb2312,tahoma,arial,宋體,sans-serif;"><span style="font-size:18.7px;">　　SO<sub>2</sub>+ H<sub>2</sub>O + R←→ RH<sup>+</sup> + HSO<sub>3</sub><sup>-</sup>　　　　 (3)</span></span></div> <div style="margin-left: 80px;"> </div> <div style="margin-left: 80px;"><span style="font-family:楷體_gb2312,tahoma,arial,宋體,sans-serif;"><span style="font-size:18.7px;">　　上式中R代表吸收劑，（3）式是可逆反應，低溫下反應（3）從左向右進(jìn)行，高溫下反應（3）從右向左進(jìn)行。復合胺（離子液）液循環(huán)吸收法正是利用此原理，在低溫下吸收二氧化硫，高溫下將吸收劑中二氧化硫再生出來(lái)，從而達到脫除和回收煙氣中SO<sub>2</sub>的目的。</span></span></div> <div style="margin-left: 80px;"> </div> <div style="margin-left: 80px;"><span style="font-family:楷體_gb2312,tahoma,arial,宋體,sans-serif;"><span style="font-size:18.7px;">　　“復合胺（離子液）液循環(huán)吸收法脫除和回收煙氣中二氧化硫技術(shù)”，克服了傳統復合胺（離子液）液體的缺點(diǎn)，是一種新穎的復合胺（離子液）液體技術(shù)與傳統的“吸收――再生”氣體凈化工藝的完美相合。該技術(shù)采用的吸收劑蒸汽壓極低，吸收劑再生時(shí)產(chǎn)生高純SO<sub>2</sub>氣體。本工藝副產(chǎn)的高純SO<sub>2</sub>氣體是液體SO<sub>2</sub>、硫酸、硫磺和其它硫化工產(chǎn)品的優(yōu)良原料。該技術(shù)具有自主知識產(chǎn)權，所有設備均可實(shí)現國產(chǎn)化。</span></span></div> <div style="margin-left: 80px;"> </div> <div style="margin-left: 80px;"><span style="font-family:楷體_gb2312,tahoma,arial,宋體,sans-serif;"><span style="font-size:18.7px;">　　本公司開(kāi)發(fā)的離子液，經(jīng)國家權威部門(mén)檢測，無(wú)毒、無(wú)害、不燃、不爆，符合環(huán)保業(yè)的要求。</span></span></div> <div style="margin-left: 80px;"> </div> <div style="margin-left: 80px;"><span style="font-family:楷體_gb2312,tahoma,arial,宋體,sans-serif;"><span style="font-size:18.7px;"><strong>　　原則流程圖</strong></span></span></div> <div style="margin-left: 80px;"> </div> <div style="text-align: center; margin-left: 80px;"><span style="font-family:楷體_gb2312,tahoma,arial,宋體,sans-serif;"><span style="font-size:18.7px;"><img class="imageResponse js-onerror" domain-src="/repository/image/VKqfxqzLSTi2BS7-hnixUg.png" id="54" src="/repository/image/VKqfxqzLSTi2BS7-hnixUg.png" /></span></span></div> <div style="margin-left: 80px;"> </div> <div style="margin-left: 80px;"><span style="font-family:楷體_gb2312,tahoma,arial,宋體,sans-serif;"><span style="font-size:18.7px;"><strong>　　技術(shù)特點(diǎn)</strong></span></span></div> <div style="margin-left: 80px;"> </div> <div style="margin-left: 80px;"><span style="font-family:楷體_gb2312,tahoma,arial,宋體,sans-serif;"><span style="font-size:18.7px;"><strong>　　1 技術(shù)先進(jìn)性</strong></span></span></div> <div style="margin-left: 80px;"><span style="font-family:楷體_gb2312,tahoma,arial,宋體,sans-serif;"><span style="font-size:18.7px;">　?、倜摿蛐矢撸好摿蛐士蛇_99.5% ,且脫硫效率可靈活調節。</span></span></div> <div style="margin-left: 80px;"><span style="font-family:楷體_gb2312,tahoma,arial,宋體,sans-serif;"><span style="font-size:18.7px;">　?、谶m應范圍寬：在煙氣含硫量從0.02% 到5%的范圍內運行成本穩定，對各類(lèi)煙氣無(wú)限制。在煙氣中硫含量較高時(shí)，本技術(shù)的投資和操作成本更具優(yōu)勢。</span></span></div> <div style="margin-left: 80px;"><span style="font-family:楷體_gb2312,tahoma,arial,宋體,sans-serif;"><span style="font-size:18.7px;">　?、勰芎牡停涸偕λ谜羝蟮?，可利用工廠(chǎng)的低品位廢熱。</span></span></div> <div style="margin-left: 80px;"><span style="font-family:楷體_gb2312,tahoma,arial,宋體,sans-serif;"><span style="font-size:18.7px;">　?、芟到y運行可靠：工藝流程經(jīng)典、簡(jiǎn)潔，自動(dòng)化程度高，可實(shí)現三年無(wú)系統故障運行。</span></span></div> <div style="margin-left: 80px;"><span style="font-family:楷體_gb2312,tahoma,arial,宋體,sans-serif;"><span style="font-size:18.7px;">　?、葸\行簡(jiǎn)便：開(kāi)停車(chē)方便，調試和維修費用低。</span></span></div> <div style="margin-left: 80px;"> </div> <div style="margin-left: 80px;"><span style="font-family:楷體_gb2312,tahoma,arial,宋體,sans-serif;"><span style="font-size:18.7px;"><strong>　　2 環(huán)保實(shí)效性</strong></span></span></div> <div style="margin-left: 80px;"><span style="font-family:楷體_gb2312,tahoma,arial,宋體,sans-serif;"><span style="font-size:18.7px;">　?、贌o(wú)二次污染：場(chǎng)地無(wú)粉塵, 無(wú)強噪聲，無(wú)新生固體、氣體和液體排放物。</span></span></div> <div style="margin-left: 80px;"><span style="font-family:楷體_gb2312,tahoma,arial,宋體,sans-serif;"><span style="font-size:18.7px;">　?、谖找嚎稍偕?，循環(huán)使用，損耗低。</span></span></div> <div style="margin-left: 80px;"><span style="font-family:楷體_gb2312,tahoma,arial,宋體,sans-serif;"><span style="font-size:18.7px;">　?、鄹碑a(chǎn)國內資源相對貧缺的副產(chǎn)品：副產(chǎn)品為99%干基的SO<sub>2</sub>，可作為液體二氧化硫、硫酸、硫磺或其它硫化工產(chǎn)品的優(yōu)良原料。</span></span></div> <div style="margin-left: 80px;"><span style="font-family:楷體_gb2312,tahoma,arial,宋體,sans-serif;"><span style="font-size:18.7px;">　?、墉h(huán)保前瞻性：在脫除SO<sub>2</sub>、NOx、Hg、As同時(shí)，不釋放NH<sub>3</sub>、CO<sub>2</sub>,符合環(huán)保發(fā)展趨勢。</span></span></div> <div style="margin-left: 80px;"> </div> <div style="margin-left: 80px;"><span style="font-family:楷體_gb2312,tahoma,arial,宋體,sans-serif;"><span style="font-size:18.7px;"><strong>　　3 經(jīng)濟可行性</strong></span></span></div> <div style="margin-left: 80px;"><span style="font-family:楷體_gb2312,tahoma,arial,宋體,sans-serif;"><span style="font-size:18.7px;">　?、俟澕s運力：無(wú)需常規的大量運輸，無(wú)需規劃運輸/堆倉用地。</span></span></div> <div style="margin-left: 80px;"><span style="font-family:楷體_gb2312,tahoma,arial,宋體,sans-serif;"><span style="font-size:18.7px;">　?、谀芎妮^低：電耗低，可采用廢熱實(shí)現再生。</span></span></div> <div style="margin-left: 80px;"><span style="font-family:楷體_gb2312,tahoma,arial,宋體,sans-serif;"><span style="font-size:18.7px;">　?、壅嫉孛娣e?。捍蠓鶞p少煙氣脫硫設施的土地使用面積。</span></span></div> <div style="margin-left: 80px;"><span style="font-family:楷體_gb2312,tahoma,arial,宋體,sans-serif;"><span style="font-size:18.7px;">　?、苊摿蛟O施運行費用較低，且不隨煙氣中硫含量上升而明顯增加。</span></span></div> <div style="margin-left: 80px;"><span style="font-family:楷體_gb2312,tahoma,arial,宋體,sans-serif;"><span style="font-size:18.7px;">　?、菖c傳統方法相比，綜合經(jīng)濟指標具有明顯優(yōu)勢。</span></span></div> <div style="margin-left: 80px;"> </div> <div style="margin-left: 80px;"><span style="font-family:楷體_gb2312,tahoma,arial,宋體,sans-serif;"><span style="font-size:18.7px;"><strong>　　4 自主知識產(chǎn)權</strong></span></span></div> <div style="margin-left: 80px;"><span style="font-family:楷體_gb2312,tahoma,arial,宋體,sans-serif;"><span style="font-size:18.7px;">　?、贀碛型耆淖灾髦R產(chǎn)權。</span></span></div> <div style="margin-left: 80px;"><span style="font-family:楷體_gb2312,tahoma,arial,宋體,sans-serif;"><span style="font-size:18.7px;">　?、谒性O備均可實(shí)現國產(chǎn)化。</span></span></div> <div style="margin-left: 80px;"> </div> <div style="text-align: center; margin-left: 80px;"><u><span style="font-family:NSimSun;"><em><span style="font-size:20pt;"><span style="color:#00cccc;">{</span><a href="/comp/xcompanyFile/download.do?fid=6&appId=24&id=6" se_prerender_url="loading" target="_blank"><span style="color:#00cccc;">復合胺（離子液）脫硫交流資料.ppt</span></a><span style="color:#00cccc;">}</span></span></em></span></u></div> <div style="margin-left: 80px;"> </div> <h3 style="text-align: center; margin-left: 80px;"> </h3> <h3 style="text-align: center; margin-left: 80px;"><span id="g3gg5xt16r9" class="normalPara" style="text-align:center;"><span style="font-size:22px;"><span style="font-family:微軟雅黑體,tahoma,arial,sans-serif;"><strong>氨法煙氣脫硫技術(shù)</strong></span></span></span></h3> <div style="margin-left: 80px;"><span style="font-family:楷體_gb2312,tahoma,arial,宋體,sans-serif;"><span style="font-size:18.7px;"><strong>　　概述</strong></span></span></div> <div style="margin-left: 80px;"><span style="font-family:楷體_gb2312,tahoma,arial,宋體,sans-serif;"><span style="font-size:18.7px;">　　氨是一種良好的堿性吸收劑，其脫硫能力遠超過(guò)石灰石-石膏法和海水法，脫硫效率可以達到98%以上，即使燃用高硫煤種，也可滿(mǎn)足2011年國家新頒布的排放標準。2005年以后，氨法脫硫技術(shù)在國內的應用業(yè)績(jì)逐年增多，特別是在化工、石化企業(yè)尤為顯著(zhù)。</span></span></div> <div style="margin-left: 80px;"><span style="font-family:楷體_gb2312,tahoma,arial,宋體,sans-serif;"><span style="font-size:18.7px;"><strong>　　技術(shù)特點(diǎn)：</strong></span></span></div> <div style="margin-left: 80px;"><span style="font-family:楷體_gb2312,tahoma,arial,宋體,sans-serif;"><span style="font-size:18.7px;">　　1. 脫硫效率高，可以輕易達到99%以上的脫硫效率，更易于達到排放標準。</span></span></div> <div style="margin-left: 80px;"><span style="font-family:楷體_gb2312,tahoma,arial,宋體,sans-serif;"><span style="font-size:18.7px;">　　2. 脫硫塔不易結垢，由于氨具有更高的反應活性，且硫酸銨極易溶解的化學(xué)特性，決定了氨法脫硫系統可以避免結垢。</span></span></div> <div style="margin-left: 80px;"><span style="font-family:楷體_gb2312,tahoma,arial,宋體,sans-serif;"><span style="font-size:18.7px;">　　3. 氨法對煤中硫含量適應性廣，氨法脫硫對煤中硫含量的適應性廣，低、中、高硫含量的煤種脫硫均能適應，特別適合于中高硫煤的脫硫。采用石灰石/石膏法時(shí)，煤的含硫量越高，石灰石用量就越大，費用也就越高；而采用氨法時(shí)，特別是采用廢氨水作為脫硫吸收劑時(shí)，由于脫硫副產(chǎn)物的價(jià)值較高，煤中含硫量越高，脫硫副產(chǎn)品硫酸銨的產(chǎn)量越大，也就越經(jīng)濟。</span></span></div> <div style="margin-left: 80px;"><span style="font-family:楷體_gb2312,tahoma,arial,宋體,sans-serif;"><span style="font-size:18.7px;">　　4. 無(wú)二次污染，采用石灰石/石膏法時(shí)，脫硫過(guò)程中會(huì )釋放出溫室氣體---二氧化碳（每脫除一噸二氧化硫要釋放出0.7噸二氧化碳），同時(shí)會(huì )產(chǎn)生脫硫廢水，形成二次污染；氨法脫硫過(guò)程中不僅副產(chǎn)品可以做為肥料，而且不產(chǎn)生廢水。</span></span></div> <div style="margin-left: 80px;"><span style="font-family:楷體_gb2312,tahoma,arial,宋體,sans-serif;"><span style="font-size:18.7px;">　　5. 系統簡(jiǎn)單、設備體積小、能耗低。</span></span></div> <div style="margin-left: 80px;"><span style="font-family:楷體_gb2312,tahoma,arial,宋體,sans-serif;"><span style="font-size:18.7px;">　　6. 采用特殊氨捕集技術(shù)，氨逃逸濃度小。</span></span></div> <div> </div> <div><span style="color:#b22222;"><span style="font-size:20pt;"><u><strong><a href="/intro/12.html" se_prerender_url="complete" target="_blank">該技術(shù)成功案例——點(diǎn)擊瀏覽</a></strong></u></span></span></div> <div style="text-align: center;"> </div> <div> </div> <div> </div> <div> </div> </div> </div> </div> <div id="g3gg5xt16r9" class="e_box p_assist"> <div 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